Carbon dioxide clathrate hydrate formation at low temperature

The formation and presence of clathrate hydrates could influence the composition stability planetary ices comets; they are at heart development numerous complex models, all which include necessary condition imposed by their curves, some cage occupancy or host-guest content hydration number, but fewer take into account kinetics aspects. We measure temperature-dependent-diffusion-controlled carbon dioxide hydrate in 155-210~K range order to establish low temperature. exposed thin water ice films a few microns thickness deposited dedicated infrared transmitting closed cell gaseous maintained pressure times is thermodynamically stable. time dependence was monitored with recording specific vibrational modes CO2 Fourier Transform InfraRed (FTIR) spectrometer. These experiments clearly show two-step formation, particularly temperature, within relatively simple geometric configuration. satisfactorily applied model combining surface clathration followed bulk diffusion-relaxation growth process derived temperature-dependent-diffusion coefficient for spreading clathrate. apparent activation energy corresponding this considered temperature E_a = 24.7 +/- 9.7 kJ/mol. parameters favour possible nucleation mainly planets satellites.